With the growth of radio frequency niobium superconducting cavity design, it is widely used in national and international world. The requests for niobium are also increased. Absolute pure metal only exists theoretically. Actually the metals we are applying more or less have impurities. Superconducting niobium usually contains O, C, N, H and Ta, Fe, W and etc. If the impurities are over limited range, the properties of superconducting niobium itself will be affected. Then its value will be influenced as high purity niobium superconducting material. Therefore, niobium RRR data is an important parameter to reflect purity and thermal conductance.